Tetranuclear Cr–Ln ferrocenecarboxylate complexes with a defect-dicubane structure: synthesis, magnetism, and thermolysis-Reference-Cited by-同舟云学术

Tetranuclear Cr–Ln ferrocenecarboxylate complexes with a defect-dicubane structure: synthesis, magnetism, and thermolysis

Published:2021 Issue:46 Volume:50 Page:16990-16999
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Koroteev Pavel S.¹^ORCID,Dobrokhotova Zhanna V.¹,Ilyukhin Andrey B.¹,Belova Ekaterina V.¹²,Yapryntsev Alexey D.¹,Rouzières Mathieu³,Clérac Rodolphe³^ORCID,Efimov Nikolay N.¹^ORCID

Affiliation:

1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky prosp. 31, 119991 Moscow, Russian Federation

2. Lomonosov Moscow State University, Department of Chemistry, GSP-1, Leninskie Gory 1/3, 119991 Moscow, Russian Federation

3. Univ. Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, 33600 Pessac, France

Abstract

New Cr–Fe–Ln complexes with ferrocenecarboxylate and triethanolamine ligands are obtained. Tb, Dy and Ho complexes are SMMs, and Dy one has the anisotropy barrier of 75 K. Thermolysis of complexes leads to Cr0.75Fe1.25O3 and LnCr0.25Fe0.75O3 phases.

Funder

Centre National de la Recherche Scientifique

Université de Bordeaux

Conseil Régional Aquitaine

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02562G

Reference82 articles.