Ferrocenyl-based di- and trinuclear lanthanide complexes: solid state structures, (spectro)electrochemical and DFT studies-Reference-Cited by-同舟云学术

Ferrocenyl-based di- and trinuclear lanthanide complexes: solid state structures, (spectro)electrochemical and DFT studies

Published:2023 Issue:47 Volume:52 Page:17717-17730
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Khalladi Ahmed¹,Kovalski Eduard¹,Abdulmalic Mohammad A.¹,Rüffer Tobias²^ORCID,Yuan Qing¹,Naïli H.³,Korb Marcus⁴^ORCID,Lang Heinrich¹^ORCID

Affiliation:

1. Technische Universität, Research Centre for Materials, Architectures and Integration of Nanomembranes (MAIN), Research Group Organometallic Chemistry, Rosenbergstraße 6, D-09126 Chemnitz, Germany

2. Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany

3. University of Sfax, Faculty of Sciences, Department of Chemistry, Solid State Physico-Chemistry Laboratory, PB 1171, 3000 Sfax, Tunisia

4. School of Molecular Sciences, The University of Western Australia, Crawley, Perth, WA 6009, Australia

Abstract

Reaction of ferrocenyl carboxylic acid with lanthanide salts gave di- and trimeric complexes bearing 6 and 9 organometallics. Square wave voltammetry and DFT studies showed that electrostatic repulsion determines the distribution of redox events.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00812F

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