Direct stereoselective construction of cyclopropane α-amino acid with contiguous quaternary centers via [4 + 2] annulation reaction-Reference-Cited by-同舟云学术

Direct stereoselective construction of cyclopropane α-amino acid with contiguous quaternary centers via [4 + 2] annulation reaction

Published:2017 Issue:60 Volume:7 Page:38077-38080
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Hu Jun-Hao¹²³⁴⁵,Xu Yun-Chao⁶⁷⁸⁹⁵,Liu Dan-Dan⁶⁷⁸⁹⁵,Sun Bing⁶⁷⁸⁹⁵,Yi Ying⁶⁷⁸⁹⁵,Zhang Fang-Lin⁶⁷⁸⁹⁵^ORCID

Affiliation:

1. Department of Chemistry and Material Science

2. Key Laboratory of Functional Organometallic Materials of Hunan Provincial College

3. Hengyang Normal University

4. Hengyang

5. People's Republic of China

6. School of Chemistry

7. Chemical Engineering and Life Sciences

8. Wuhan University of Technology

9. Wuhan 430070

Abstract

A direct diastereoselective synthetic approach to useful cyclopropane α-amino acid was established via base-promoted [4 + 2] annulations between o-aminobenzaldehydes and alkyl 2-aroyl-1-chlorocyclopropanecarboxylates.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA06465A

Reference41 articles.

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2. Synthesis of cyclopropane containing natural products

3. Natural Occurrence, Syntheses, and Applications of Cyclopropyl-Group-Containing α-Amino Acids. 1. 1-Aminocyclopropanecarboxylic Acid and Other 2,3-Methanoamino Acids

4. Cytotrienin A, a Novel Apoptosis Inducer in Human Leukemia HL-60 Cells.

5. UCF116, New Inhibitors of Farnesyltransferase Produced by Streptomyces.

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