Hydrogen peroxide/dimethyl carbonate: a green system for epoxidation of N-alkylimines and N-sulfonylimines. One-pot synthesis of N-alkyloxaziridines from N-alkylamines and (hetero)aromatic aldehydes
Author:
Affiliation:
1. Département de chimie
2. Université Laval
3. Québec (Québec) G1V 0A6
4. Canada
5. Laboratoire de Développement Chimique
6. Galénique et Pharmacologique des Médicaments
7. Faculté de Pharmacie de Monastir
8. Université de Monastir
9. 5000 Monastir
Abstract
A green method for epoxidation of imines using an environmentally benign oxidant system, H2O2/dimethyl carbonate, was developed.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/GC/C6GC01394E
Reference55 articles.
1. The Preparation and Properties of Oxaziranes
2. Asymmetric oxygenation of chiral imide enolates. A general approach to the synthesis of enantiomerically pure .alpha.-hydroxy carboxylic acid synthons
3. Novel N-Phosphonio Imine-Catalyzed Epoxidation Reactions
4. Chemistry of oxaziridines. 10. Selective catalytic oxidation of sulfides to sulfoxides using N-sulfonyloxaziridines
5. Reaction of oxaziridine with heterocumulene. A ketene, isocyanates, and carbodiimide
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