[001]-Oriented heteroepitaxy for fabricating emissive surface mounted metal–organic frameworks

Author:

Zhao Tonghan1ORCID,Taghizade Narges2ORCID,Fischer Jan C.1,Richards Bryce S.13ORCID,Howard Ian A.13ORCID

Affiliation:

1. Institute of Microstructure Technology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

2. Institute of Solid State Physics, NAWI Graz, Graz University of Technology, Petersgasse 16, A-8010 Graz, Austria

3. Light Technology Institute, Karlsruhe Institute of Technology, Engesserstrasse 13, 76131 Karlsruhe, Germany

Abstract

A hybrid SURMOF with specific crystallographic [001] orientation is fabricated via step-by-step liquid-phase heteroepitaxial method. The preferential [001] orientation of Cu2(BDC)2(DABCO) is retained via Zn2(BDC)2(DABCO) to Zn2(ADC)2(BPy).

Funder

Helmholtz Association

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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