Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds-Reference-Cited by-同舟云学术

Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Published:2020 Issue:19 Volume:11 Page:5082-5088
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yan Chenting¹²³⁴⁵^ORCID,Takeshita Masato¹²³⁴⁵,Nakatsuji Jun-ya¹²³⁴⁵,Kurosaki Akihiro¹²³⁴⁵,Sato Kaoko¹²³⁴⁵,Shang Rong¹²³⁴⁵^ORCID,Nakamoto Masaaki¹²³⁴⁵,Yamamoto Yohsuke¹²³⁴⁵^ORCID,Adachi Yohei⁶⁷³⁴⁵^ORCID,Furukawa Ko⁸⁹¹⁰¹¹⁵,Kishi Ryohei¹²¹³¹⁴¹⁵⁵,Nakano Masayoshi¹²¹³¹⁴¹⁵⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Higashi-Hiroshima 739-8526

5. Japan

6. Department of Applied Chemistry

7. Graduate School of Engineering

8. Center for Coordination Research Facilities

9. Institute for Research Promotion

10. Niigata University

11. Niigata 950-2181

12. Department of Materials Engineering Science

13. Graduate School of Engineering Science

14. Osaka University

15. Toyonaka

Abstract

Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00002G

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