Affiliation:
1. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, 166 10 Prague 6, Czech Republic
2. Department of Organic Chemistry, Charles University, 128 00 Prague 2, Czech Republic
Abstract
Triaryl amine radical cations and trityl radicals use two completely orthogonal stabilization strategies. The former delocalize both the spin and charge density over the π-system, while the latter isolate the spin density by persistent barriers.
Funder
Grantová Agentura České Republiky
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis