Accessing distributions of exchange and dipolar couplings in stiff molecular rulers with Cu(ii) centres

Author:

Keller K.12345,Ritsch I.12345,Hintz H.6789,Hülsmann M.6789,Qi M.6789,Breitgoff F. D.12345,Klose D.12345,Polyhach Y.12345ORCID,Yulikov M.12345ORCID,Godt A.6789,Jeschke G.12345ORCID

Affiliation:

1. Laboratory of Physical Chemistry

2. Department of Chemistry and Applied Biosciences

3. ETH Zurich

4. 8093 Zurich

5. Switzerland

6. Faculty of Chemistry and Center for Molecular Materials (CM2)

7. Bielefeld University

8. 33615 Bielefeld

9. Germany

Abstract

Novel approaches to quantitatively analyse distributed exchange couplings are described and tested on experimental data sets for stiff synthetic molecules.

Funder

Deutsche Forschungsgemeinschaft

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference115 articles.

1. PULSED EPR SPECTROSCOPY: Biological Applications

2. A. Schweiger and G.Jeschke , Principles of Pulse Electron Paramagnetic Resonance , Oxford University Press , 2001

3. A. Bencini and D.Gatteschi , EPR of Exchange Coupled Systems , Springer Verlag , Berlin , 1990

4. Long-range distance determinations in biomacromolecules by EPR spectroscopy

5. DEER Distance Measurements on Proteins

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