Synthesis of mono-nitroxides and of bis-nitroxides with varying electronic through-bond communication-Reference-Cited by-同舟云学术

Synthesis of mono-nitroxides and of bis-nitroxides with varying electronic through-bond communication

Published:2023 Issue:2 Volume:21 Page:375-385
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Giannoulis Angeliki¹²^ORCID,Ackermann Katrin²^ORCID,Bogdanov Alexey¹^ORCID,Cordes David B.²^ORCID,Higgins Catherine²,Ward Joshua²,Slawin Alexandra M. Z.²^ORCID,Taylor James E.²³^ORCID,Bode Bela E.²^ORCID

Affiliation:

1. Department of Chemical and Biological Physics, Weizmann Institute of Science, Rehovot, 76100, Israel

2. EaStCHEM School of Chemistry, Biomedical Sciences Research Complex and Centre of Magnetic Resonance, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK

3. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

Abstract

The electron–electron exchange interaction (J) underpins quantum coherence phenomena. Here, synthetic strategies to moderate J in model compounds were evaluated with electron paramagnetic resonance spectroscopy.

Funder

Engineering and Physical Sciences Research Council

Wellcome Trust

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01863B

Reference51 articles.

1. Dynamically Controlled Protein Tunneling Paths in Photosynthetic Reaction Centers

2. EPR and DEER Characterization of New Mixed Weakly Coupled Nitroxide Triradicals for Molecular Three-Spin Qubits

3. PELDOR at S- and X-Band Frequencies and the Separation of Exchange Coupling from Dipolar Coupling

4. Constructive quantum interference in a bis-copper six-porphyrin nanoring

5. Measuring Spin⋅⋅⋅Spin Interactions between Heterospins in a Hybrid [2]Rotaxane

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