Synthesis, crystallographic characterization and homogeneous catalytic activity of novel unsymmetric porphyrins

Author:

Antonangelo A. R.12345ORCID,Westrup K. C. M.12345ORCID,Burt L. A.6789,Bezzu C. Grazia6789,Malewschik T.12345,Machado G. S.1011125,Nunes F. S.12345,McKeown N. B.6789,Nakagaki S.12345ORCID

Affiliation:

1. Laboratório de Bioinorgânica e Catálise

2. Departamento de Química

3. Universidade Federal do Paraná

4. Curitiba

5. Brazil

6. EastChem School of Chemistry

7. University of Edinburgh

8. Edinburgh

9. UK

10. Centro de Estudos do Mar

11. Pontal do Paraná-PR

12. Universidade Federal do Paraná (UFPR)

Abstract

Unsymmetric porphyrins containing both pentafluorophenyl (PFP = A) and 3,4-dimethoxyphenyl (DMP = B) substituents at the meso positions were prepared using Lindsey's methodology.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Universidade Federal do Paraná

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference53 articles.

1. L. R.Milgrom, The Colours of Life. An introduction to the Chemistry of Porphyrins and Related Compounds, Oxford University Press, Oxford, 1997

2. K. M.Smith, Porphyrins and metalloporphyrins: A New Edition Based on the Original Volume, ed. J. E. Falk, Elsevier Sci Pub Co, New York, 1975

3. Advances in Modern Synthetic Porphyrin Chemistry

4. K. M.Kadish, K. M.Smith and R.Guilard. The porphyrin handbook vol. 6, Applications: Past, Present and Future, Academic Press, San Diego, 2000

5. New highly brominated Mn-porphyrin: a good catalyst for activation of inert C–H bonds

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