New highly brominated Mn-porphyrin: a good catalyst for activation of inert C

New highly brominated Mn-porphyrin: a good catalyst for activation of inert C–H bonds

Published:2015 Issue:129 Volume:5 Page:106589-106598
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Santos da Silva Vinicius¹²³⁴⁵,Nakagaki Shirley⁶⁷⁸⁹⁵,Ucoski Geani Maria⁶⁷⁸⁹⁵,Idemori Ynara Marina¹²³⁴⁵,DeFreitas-Silva Gilson¹²³⁴⁵

Affiliation:

1. Departamento de Química

2. Instituto de Ciências Exatas

3. Universidade Federal de Minas Gerais

4. Belo Horizonte

5. Brazil

6. Laboratório de Bioinorgânica e Catálise

7. Departamento de Química – Centro Politécnico

8. Universidade Federal do Paraná (UFPR)

9. Curitiba

Abstract

Polybrominated Mn-porphyrin can act as a good catalyst for C–H activation. The oxidation of cyclohexane takes place with excellent selectivity and formation of 2-adamantanol is increased in adamantine oxidation.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA20690A

Reference82 articles.

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5. Metalloporphyrins as models for the cytochromes p-450

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