Exploring a new class of singlet fission fluorene derivatives with high-energy triplets

Author:

Mencaroni Letizia1ORCID,Carlotti Benedetta1ORCID,Elisei Fausto1ORCID,Marrocchi Assunta1ORCID,Spalletti Anna1ORCID

Affiliation:

1. Department of Chemistry Biology and Biotechnology and CEMIN, University of Perugia, via elce di sotto n. 8, 06123, Perugia, Italy

Abstract

We found that a stronger push–pull character favours SF, as long as the ICT does not act as a trap. The unique property of generating high-energy triplets (ca. 2 eV) via SF makes these materials outstanding candidates for photovoltaic applications.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Università degli Studi di Perugia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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