Unraveling the complex chemistry using dimethylsilane as a precursor gas in hot wire chemical vapor deposition
Author:
Affiliation:
1. Department of Chemistry
2. University of Calgary
3. Calgary, T2N 1N4 Canada
Abstract
At low filament temperatures and short reaction time, silylene chemistry dominates. The free-radical reactions become more important with increasing temperature and time.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP00275J
Reference42 articles.
1. Pyrolysis of monomethyl- and dimethylsilane. The role of molecular and radical processes
2. Kinetics of the high-temperature thermal decomposition of silanes and alkylsilanes
3. Kinetic and product studies of the thermal decomposition of dimethylsilane in a single-pulse shock tube and in a stirred flow reactor
4. Mechanism of the thermal decomposition of dimethylsilane at atmospheric pressures in the gas phase
5. Photochemistry of silicon compounds. 5. The 147-nm photolysis of dimethylsilane
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