Evolution of transition metal charge states in correlation with the structural and magnetic properties in disordered double perovskites Ca2−xLaxFeRuO6 (0.5 ≤ x ≤ 2)

Author:

Naveen Kumari1,Rom Tanmay1ORCID,Islam Shams Sohel2,Reehuis Manfred3,Adler Peter4,Felser Claudia4,Hoser Andreas3,Nath Ramesh Chandra2,Yadav Ashok Kumar5,Jha Shambhu Nath5,Bhattacharyya Dibyendu5ORCID,Schmidt Marcus4,Paul Avijit Kumar1ORCID

Affiliation:

1. Department of Chemistry, National Institute of Technology Kurukshetra, Kurukshetra-136119, India

2. School of Physics, Indian Institute of Science Education and Research, Thiruvananthapuram-695551, India

3. Helmholtz–Zentrum Berlin für Materialien und Energie, D-14109 Berlin, Germany

4. Max Planck Institute for Chemical Physics of Solids, D-01187 Dresden, Germany

5. Atomic & Molecular Physics Division, Bhabha Atomic Research Centre, Mumbai – 400 094, India

Abstract

La-based B-site disordered double perovskites, Ca2−xLaxFeRuO6, have been investigated thoroughly. The effects of A-site substitution on the charge states and electronic and magnetic properties have been determined in a series of 3d/4d perovskites.

Funder

Science and Engineering Research Board

Max-Planck-Gesellschaft

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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