Base mediated green synthesis of enantiopure 2-C-spiro-glycosyl-3-nitrochromenes-Reference-Cited by-同舟云学术

Base mediated green synthesis of enantiopure 2-C-spiro-glycosyl-3-nitrochromenes

Published:2019 Issue:1 Volume:17 Page:74-82
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Nayak Sabita¹²³⁴^ORCID,Panda Pravati¹²³⁴,Raiguru Bishnu Prasad¹²³⁴,Mohapatra Seetaram¹²³⁴,Purohit Chandra Shekhar⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Ravenshaw University

3. Cuttack

4. India

5. School of Chemical Sciences

6. National Institute of Science Education and Research

7. Bhubaneswar

Abstract

A novel green synthetic methodology has been developed to obtain enantiopure (2S)-2-C-spiro-glycosyl-3-nitrochromenes following the oxa-Michael–aldol condensation reaction of sugar derived 3-C-vinyl nitro olefins with substituted salicylaldehydes using Et₃N as a base under neat conditions at rt–40 °C.

Funder

Council of Scientific and Industrial Research

Defence Research and Development Organisation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C8OB02278J

Reference64 articles.

1. A Room Temperature Negishi Cross-Coupling Approach to C-Alkyl Glycosides

2. Recent developments in β-C-glycosides: synthesis and applications