Retro-metal-ene versus retro-Aldol: mechanistic insight into Rh-catalysed formal [3+2] cycloaddition-Reference-Cited by-同舟云学术

Retro-metal-ene versus retro-Aldol: mechanistic insight into Rh-catalysed formal [3+2] cycloaddition

Published:2018 Issue:96 Volume:54 Page:13551-13554
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Song¹²³⁴,Zhang Tao¹²³⁴,Zhu Lei¹²³⁴,Zhong Kangbao¹²³⁴,Gong Jianxian⁵⁶⁷⁸⁴^ORCID,Yang Zhen⁵⁶⁷⁸⁴^ORCID,Bai Ruopeng¹²³⁴^ORCID,Lan Yu¹²³⁴⁹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, and Chongqing Key Laboratory of Theoretical and Computational Chemistry

2. Chongqing University

3. Chongqing 400030

4. China

5. Laboratory of Chemical Genomics

6. School of Chemical Biology and Biotechnology

7. Peking University Shenzhen Graduate School

8. Shenzhen 518055

9. College of Chemistry and Molecular Engineering

Abstract

Our theoretical calculation indicated that the competition between retro-metal-ene reaction and retro-Aldol-type reaction results in the expected hexahydropentalene product together with its diastereoisomer in the newly reported rhodium-catalysed intramolecular [3+2] cycloaddition.

Funder

National Natural Science Foundation of China

Chongqing University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC08335E

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