A novel alb metalloring organic framework with a {Ni12Gd24} cage exhibiting a significant magnetocaloric effect
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fujian
5. P. R. China
Abstract
A novel {Ni12Gd24} cage-based (6, 12)-c alb–MROF built from a {Gd4(OH)4(COO)6} trigonal-prism building unit and a {Ni6S12} hexagonal-prism molecular building block has been synthesized for the first time. It exhibits a large MCE value of 29.86 J kg−1 K−1 for ΔH = 8 T at 2 K.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02358H
Reference69 articles.
1. Molecule-based magnetic coolers
2. Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants
3. Chilling with Magnetic Molecules
4. Magnetothermal properties of molecule-based materials
5. Molecular Design for Cryogenic Magnetic Coolants
Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. MoO42−-templated Ln20Ni21heterometallic clusters with large low-field magnetic entropy;Dalton Transactions;2023
2. Two SiO44–-Templated Ln23Ni20 Clusters with Magnetic Cooling and Stability;Inorganic Chemistry;2022-04-28
3. Magnetic cooling: a molecular perspective;Dalton Transactions;2022
4. Approach toward Iron(II) Coordination Polymers Based on Chain Motifs with Thiolate or Mixed Thiolate/Carboxylate Bridges: Structures and Magnetic Properties;Inorganic Chemistry;2021-12-10
5. Aliphatic amine mediated assembly of [M6(mna)6] (M = Cu/Ag) into extended two-dimensional structures: synthesis, structure and Lewis acid catalytic studies;New Journal of Chemistry;2021
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3