Intramolecular cyclization assisted oxidative addition: synthesis of octahedral cycloplatinated methyl complexes-Reference-Cited by-同舟云学术

Intramolecular cyclization assisted oxidative addition: synthesis of octahedral cycloplatinated methyl complexes

Published:2015 Issue:26 Volume:5 Page:20295-20301
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Shankar D.¹²³⁴⁵,Jaipal K.⁶²³⁴⁵,Sridhar B.⁷³⁴⁵,Chary R. Nagarjuna⁸³⁴⁵,Prabhakar S.⁸³⁴⁵,Giribabu L.⁶²³⁴⁵,Likhar Pravin R.¹²³⁴⁵

Affiliation:

1. Organometallic Gp.

2. Inorganic and Physical Chemistry Division

3. CSIR-Indian Institute of Chemical Technology

4. Hyderabad-500007

5. India

6. Solar Cell Gp.

7. X-ray Crystallography Centre

8. National Centre for Mass Spectrometry

Abstract

Cycloplatination of XMeC₆H₄CCC-(R_f) (N-4-OCH₃C₆H₄) [X = S, Se and R_f = perfluoroalkyl groups] with PtCl₂ gave a monomeric octahedral Pt(iv) complex. Emission and reactivity studies of the Pt(iv) complexes are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA17066K

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