Reactivity comparison of five-and six-membered cyclometalated platinum(ii) complexes in oxidative addition reactions-Reference-Cited by-同舟云学术

Reactivity comparison of five-and six-membered cyclometalated platinum(ii) complexes in oxidative addition reactions

Published:2015 Issue:103 Volume:5 Page:85111-85121
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Raoof Fatemeh¹²³⁴⁵,Boostanizadeh Maryam¹²³⁴⁵,Esmaeilbeig Ahmad R.¹²³⁴⁵,Nabavizadeh S. Masoud¹²³⁴⁵,Aghakhanpour Reza Babadi¹²³⁴⁵,Ghiassi Kamran B.¹⁶⁷⁸,Olmstead Marilyn M.¹⁶⁷⁸,Balch Alan L.¹⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. College of Sciences

3. Shiraz University

4. Shiraz 71467-13565

5. Iran

6. University of California

7. Davis

8. USA

Abstract

A six-membered cyclometalated complex [PtMe(bzpy)(PPh₃)] (bzpy = 2-benzylpyridinate) undergoes oxidative addition with methyl iodide to give [PtMe₂I(bzpy)(PPh₃)]. The ring size of the chelating unit has a significant impact on the rate of the reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17421J

Reference31 articles.

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2. Reactivity of a Dimethylplatinum(II) Complex with the Bis(2-pyridyl)dimethylsilane Ligand: Easy Silicon–Carbon Bond Activation

3. Synthesis, characterization and electrochemiluminescent properties of cyclometalated platinum(ii) complexes with substituted 2-phenylpyridine ligands

4. Synthesis and Photophysical Properties of Cyclometalated Platinum(II) 1,2-Benzenedithiolate Complexes and Heterometallic Derivatives Obtained from the Addition of [Au(PCy3)]+ Units

5. Photoluminescence and trans → cis Photoisomerization of Aminostyrene-Conjugated Phenylpyridine C^N Ligands and Their Complexes with Platinum(II): The Styryl Position and the Amino Substituent Effects

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