Water induces the same crown shapes as Li+ or Na+ in 15-crown-5 ether: a broadband rotational study

Author:

López Juan C.12345ORCID,Pérez Cristóbal12367ORCID,Blanco Susana458910ORCID,Shubert V. Alvin123,Temelso Berhane11121314ORCID,Shields George C.11121314ORCID,Schnell Melanie123ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron (DESY)

2. Hamburg

3. Germany

4. Departamento de Química Física y Química Inorgánica

5. Facultad de Ciencias

6. Facultad de Ciencia y Tecnología

7. Universidad del País Vasco (UPV-EHU)

8. Universidad de Valladolid

9. Valladolid

10. Spain

11. Provost's Office and Department of Chemistry

12. Furman University

13. Greenville

14. USA

Abstract

Complexation with water reduces the structural landscape of 15-crown-5 ether to the two forms observed for Li+ or Na+ complexes.

Funder

Deutsche Forschungsgemeinschaft

National Science Foundation

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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1. Molecular Structure of Salicylic Acid and Its Hydrates: A Rotational Spectroscopy Study;International Journal of Molecular Sciences;2024-04-06

2. Mechanism for lithium extraction with ether and ester oxygens in armed crown ethers;Journal of Molecular Liquids;2024-04

3. Conformational isomerism in trans-3-methoxycinnamic acid: From solid to gas phase;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2024-04

4. Thermodynamics of Li+–Crown Ether Interactions in Aqueous Solvent;The Journal of Physical Chemistry A;2023-05-17

5. Electrophilic substitution reactivity prediction of crown ether derivatives;Journal of Physical Organic Chemistry;2023-04-23

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