Hydroxido supported and differently networked octanuclear Ni6Ln2 [Ln = GdIII and DyIII] complexes: structural variation, magnetic properties and theoretical insights

Author:

Bhanja Avik1234ORCID,Smythe Lucy56789,Herchel Radovan1011121314ORCID,Nemec Ivan1011121314ORCID,Murrie Mark56789ORCID,Ray Debashis1234ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Kharagpur 721302

4. India

5. School of Chemistry

6. University of Glasgow

7. University Avenue

8. Glasgow G12 8QQ

9. UK

10. Department of Inorganic Chemistry

11. Faculty of Science

12. Palacky University

13. CZ-771 46 Olomouc

14. Czech Republic

Abstract

Solvent derived hydroxido bridge driven Ni6Ln2 [Ln = GdIII (1) and DyIII (2)] coordination aggregates of two different types has been synthesized. Magnetic susceptibility study confirms field induced slow relaxation of magnetization for Ni6Dy2.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

University of Glasgow

Univerzita Palackého v Olomouci

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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