Insight into ferromagnetic interactions in Cu<sup>II</sup>–Ln<sup>III</sup> dimers with a compartmental ligand-Reference-Cited by-同舟云学术

Insight into ferromagnetic interactions in Cu^II–Ln^III dimers with a compartmental ligand

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Panja Anangamohan¹²^ORCID,Paul Sagar³^ORCID,Moreno-Pineda Eufemio⁴⁵^ORCID,Herchel Radovan⁶^ORCID,Jana Narayan Ch.²^ORCID,Brandão Paula⁷^ORCID,Novitchi Ghenadie⁸,Wernsdorfer Wolfgang³⁹^ORCID

Affiliation:

1. Department of Chemistry, Gokhale Memorial Girls’ College, 1/1 Harish Mukherjee Road, Kolkata-700020, India

2. Department of Chemistry, Panskura Banamali College, Panskura RS, WB 721152, India

3. Physikalisches Institut, Karlsruhe Institute of Technology, D-76131 Karlsruhe, Germany

4. Universidad de Panamá, Facultad de Ciencias Naturales, Exactas y Tecnología, Depto. de Química-Física, 0824 Panamá, Panama

5. Universidad de Panamá, Facultad de Ciencias Naturales, Exactas y Tecnología, Grupo de Investigación de Materiales, 0824 Panamá, Panama

6. Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 77146 Olomouc, Czech Republic

7. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

8. Laboratoire National des Champs Magnétiques Intenses, UPR CNRS 3228, Université Grenoble-Alpes, B.P. 166, 38042 Grenoble Cedex 9, France

9. Institute for Quantum Materials and Technology (IQMT), Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen D-76344, Germany

Abstract

A series of heterobimetallic ferromagnetically coupled CuII-LnIII systems with a new compartmental Schiff base ligand has been explored by SQUID and μ-SQUID studies. CASSCF calculations allow quantitative assessment of the interactions, which are further supported by BS-DFT calculations.

Funder

CouncilofScientific and Industrial Research, India

Fundação para a Ciência e a Tecnologia

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

H2020 European Research Council

Univerzita Palackého v Olomouci

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry