Nickel-catalysed regio- and stereoselective hydrocyanation of alkynoates and its mechanistic insights proposed by DFT calculations-Reference-Cited by-同舟云学术

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Nickel-catalysed regio- and stereoselective hydrocyanation of alkynoates and its mechanistic insights proposed by DFT calculations

Published:2024 Issue:18 Volume:22 Page:3606-3610
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Arai Shigeru¹²^ORCID,Nakazawa Koichi¹,Yang Xiao-Fei¹,Nakajima Masaya¹³,Harada Shinji¹²⁴^ORCID,Nishida Atsushi¹

Affiliation:

1. Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1 Inohana, Chuo-ku, Chiba, 260-8675, Japan

2. Molecular Chirality Research Center, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan

3. Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

4. Institute for Advanced Academic Research, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Abstract

This work discloses the origin of regio- and stereoselectivity of hydrocyanation of alkynoates.

Funder

Japan Society for the Promotion of Science

Naito Foundation

Chiba University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00380B

Reference63 articles.

1. Nitrile-Containing Pharmaceuticals: Efficacious Roles of the Nitrile Pharmacophore

2. Metal-mediated C–CN Bond Activation in Organic Synthesis

3. Recent Advances in the Synthesis of Aryl Nitrile Compounds

4. Photo-induced radical transformations of tosyl cyanide

5. Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

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