Non-symmetrical aryl- and arylethynyl-substituted thioalkyl-porphyrazines for optoelectronic materials: synthesis, properties, and computational studies-Reference-Cited by-同舟云学术

Non-symmetrical aryl- and arylethynyl-substituted thioalkyl-porphyrazines for optoelectronic materials: synthesis, properties, and computational studies

Published:2015 Issue:5 Volume:44 Page:2191-2207
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Belviso Sandra¹²³⁴⁵,Amati Mario¹²³⁴⁵,Rossano Rocco¹²³⁴,Crispini Alessandra⁶⁷⁸⁹¹⁰,Lelj Francesco¹²³⁴⁵

Affiliation:

1. Università della Basilicata

2. Dipartimento di Scienze

3. 85100 Potenza

4. Italy

5. LASCAMM

6. Centro di Eccellenza CEMIF.CAL-LASCAMM

7. CR-INSTM

8. Università della Calabria

9. Dipartimento di Chimica e Tecnologie Chimiche

10. Arcavacata di Rende

Abstract

The porphyrazine ring shows ambivalent behavior, acting either as an electron acceptor or electron donor in NMe₂ or NO₂ substituted compounds, respectively. Therefore, even this macrocycle mono-substitution provides an unconventional “push–pull” system.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03317E

Reference113 articles.

1. Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds

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4. Synthesis, Characterization, and Nonlinear Optical Study of Metalloporphyrins

5. R. W. Boyd , Nonlinear Optics, Academic Press, San Diego, CA, 1992

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