Inherently chiral helicene-substituted thioalkyl porphyrazine complexes: synthesis and electronic and chiroptical properties-Reference-Cited by-同舟云学术

Inherently chiral helicene-substituted thioalkyl porphyrazine complexes: synthesis and electronic and chiroptical properties

Published:2022 Issue:43 Volume:51 Page:16453-16464
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Belviso Sandra¹^ORCID,Marsico Giulia¹^ORCID,Franzini Roberta²^ORCID,Villani Claudio²^ORCID,Abbate Sergio³⁴^ORCID,Longhi Giovanna³⁴^ORCID

Affiliation:

1. Dipartimento di Scienze, Università della Basilicata, Viale dell'Ateneo Lucano 10, 85100 Potenza, Italy

2. Dipartimento di Chimica e Tecnologie del Farmaco, Università di Roma “La Sapienza”, Piazzale Aldo Moro 5, 00185 Roma, Italy

3. Dipartimento di Medicina Molecolare e Traslazionale, Università di Brescia, Viale Europa 11, 25123 Brescia, Italy

4. I.N.O.-CNR Unit of Brescia, c/o CSMT via Branze, 45-25123 Brescia, Italy

Abstract

Chiral helicene-substituted porphyrazine metal complexes display HOMO–LUMO charge-transfer transitions from helicenes to macrocycles, being mono-substituted push–pull systems. The absolute configuration of enantiomers is established by ECD computations.

Funder

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02665A

Reference86 articles.

1. Enantiomeric Natural Products: Occurrence and Biogenesis

2. Emerging Chiral Materials

3. The added value of small-molecule chirality in technological applications

4. Multifunctional Molecular Materials , ed. L. Ouahab , Jenny Stanford Publishing , 2013

5. H.Amouri and M.Gruselle , Chirality in Transition Metal Chemistry: Molecules, Supramolecular Assemblies and Materials , Wiley , Chichester, U.K. , 2008

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