CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron-Reference-Cited by-同舟云学术

CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron

Published:2014 Issue:26 Volume:50 Page:3498-3500
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Hooper Thomas N.¹²³,Inglis Ross¹²³,Palacios Maria A.¹²³,Nichol Gary S.¹²³,Pitak Mateusz B.⁴⁵⁶⁷⁸,Coles Simon J.⁴⁵⁶⁷⁸,Lorusso Giulia⁹¹⁰¹¹¹²,Evangelisti Marco⁹¹⁰¹¹¹²,Brechin Euan K.¹²³

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh, UK

4. UK National Crystallography Service

5. Chemistry

6. Faculty of Natural & Environmental Sciences

7. University of Southampton

8. Southampton SO17 1BJ, UK

9. Instituto de Ciencia de Materiales de Aragón

10. CSIC-Universidad de Zaragoza

11. Departamento de Física de la Materia Condensada

12. Zaragoza, Spain

Abstract

A CO₃²⁻-panelled [Gd^III₆Cu^II₃] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO₂ through a solution of Gd^III and Cu^II ions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC00141A

Reference37 articles.

1. New Tricks for an Old Dog: The Carbonate Ion as a Building Block for Networks Including Examples of Composition [Cu6(CO3)12{C(NH2)3}8]4 with the Sodalite Topology

2. Serendipity and Design in the Generation of New Coordination Polymers: An Extensive Series of Highly Symmetrical Guanidinium-Templated, Carbonate-Based Networks with the Sodalite Topology

3. CARBONATO COMPLEXES: MODELS FOR CARBONIC ANHYDRASE

4. A π–π 3D network of tetranuclear μ2/μ3-carbonato Dy(iii) bis-pyrazolylpyridine clusters showing single molecule magnetism features

5. Fixation of atmospheric CO2by a dimeric lanthanum hydroxide complex; assembly of an unusual hexameric carbonate

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