Further synthetic investigation of the general lanthanoid(iii) [Ln(iii)]/copper(ii)/pyridine-2,6-dimethanol/carboxylate reaction system: {CuII5LnIII4} coordination clusters (Ln = Dy, Tb, Ho) and their yttrium(iii) analogue-Reference-Cited by-同舟云学术

Further synthetic investigation of the general lanthanoid(iii) [Ln(iii)]/copper(ii)/pyridine-2,6-dimethanol/carboxylate reaction system: {CuII5LnIII4} coordination clusters (Ln = Dy, Tb, Ho) and their yttrium(iii) analogue

Published:2021 Issue:1 Volume:50 Page:240-251
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dermitzaki Despina¹²³⁴⁵,Raptopoulou Catherine P.⁵⁶⁷⁴^ORCID,Psycharis Vassilis⁵⁶⁷⁴^ORCID,Escuer Albert⁸⁹¹⁰¹¹¹²^ORCID,Perlepes Spyros P.¹²³⁴¹³,Mayans Julia¹⁴¹⁵¹⁶¹²^ORCID,Stamatatos Theocharis C.¹²³⁴¹³^ORCID

Affiliation:

1. Department of Chemistry

2. University of Patras

3. 26504 Patras

4. Greece

5. Institute of Nanoscience and Nanotechnology

6. NCSR “Demokritos”

7. 15310 Aghia Paraskevi Attikis

8. Departament de Química Inorgànica i Orgànica

9. Secció Inorgànica and Institut de Nanociència i Nanotecnologia (IN2UB)

10. Universitat de Barcelona

11. 08028-Barcelona

12. Spain

13. Institute of Chemical Engineering Sciences

14. Instituto de Ciencia Molecular (ICMol)

15. Universidad de Valencia

16. 46980 Paterna

Abstract

A new family of {Cu₅Ln₄} complexes bearing the dianionic form of pyridine-2,6-dimethanol (pdm²⁻) and ancillary Bu^tCH₂CO₂⁻ carboxylate groups is reported and magnetically studied.

Funder

Ministerio de Economía y Competitividad

National Council for Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03582C

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2. The crystal structure of LaFe(CN)6.5H2O