Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks-Reference-Cited by-同舟云学术

Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks

Published:2014 Issue:17 Volume:43 Page:6339-6352
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Whitehorne Todd J. J.¹²³⁴,Vabre Boris¹²³⁴,Schaper Frank¹²³⁴

Affiliation:

1. Centre in Green Chemistry and Catalysis (CGCC)

2. Département de chimie

3. Université de Montréal

4. Montréal, Canada

Abstract

Subtle variations in the substitution pattern of N-alkyl diketiminate complexes significantly change their performance in lactide polymerization. ortho-Substitution increases activity, ligand chlorination increases selectivity for Mg diketiminate complexes, while Zn diketiminate complexes react differently.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53278J

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