Homoleptic and heteroleptic ketodiiminate zinc complexes for the ROP of cyclic <scp>l</scp>-lactide-Reference-Cited by-同舟云学术

Homoleptic and heteroleptic ketodiiminate zinc complexes for the ROP of cyclic l-lactide

Published:2023 Issue:43 Volume:13 Page:29879-29885
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Glöckler Eduard¹,Kapp Leon¹,Wölper Christoph¹,Schumacher Marcel²^ORCID,Gröschel André H.²^ORCID,Schulz Stephan¹³^ORCID

Affiliation:

1. Faculty of Chemistry, University of Duisburg-Essen, Universitätsstraße 7, 45141 Essen, Germany

2. Faculty of Chemistry, University of Münster and Center for Soft Nanoscience (SoN), Busso-Peus-Strasse 10, 48149 Münster, Germany

3. Center for Nanointegration Duisburg-Essen (CENIDE), Carl-Benz-Straße 199, 47057 Duisburg, Germany

Abstract

We report the structures and activity of homo- and heteroleptic ketodiiminate zinc complexes in the ring-opening polymerization of l-lactide. Homobimetallic complex 2 selectively gave cyclic polylactide, while linear polymers were formed with mononuclear complex 3.

Funder

Deutsche Forschungsgemeinschaft

Universität Duisburg-Essen

Evonik Industries

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA06529D

Reference52 articles.

1. Sustainable polymers from renewable resources

2. The irruption of polymers from renewable resources on the scene of macromolecular science and technology

3. Synthesis of biodegradable polymers from renewable resources

4. From Lactic Acid to Poly(lactic acid) (PLA): Characterization and Analysis of PLA and Its Precursors

5. Synthesis Structure and Properties of Poly(lactid acid) , ed. M. L. Di Lorenzo and R. Androsch , Springer International Publishing , 2018 , p. 303

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