Direct conversion of secondary propargyl alcohols into 1,3-di-arylpropanone via DBU promoted redox isomerization and palladium assisted chemoselective hydrogenation in a single pot operation-Reference-Cited by-同舟云学术

Direct conversion of secondary propargyl alcohols into 1,3-di-arylpropanone via DBU promoted redox isomerization and palladium assisted chemoselective hydrogenation in a single pot operation

Published:2021 Issue:38 Volume:45 Page:17871-17877
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

De Rimpa¹,Savarimuthu S. Antony²,Chandra Shubhadeep³,Bera Mrinal K.¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Engineering Science and Technology (IIEST), Shibpur P.O. – Botanic Garden, Howrah-711 103, WB, India

2. Department of Chemistry, St. Xavier's College (Autonomous), Palayamkottai, Tamil Nadu-627 002, India

3. Institute of Inorganic Chemistry, Universitat Stuttgart, Pfaffenwaldring 55, D-, 70569, Stuttgart, Germany

Abstract

Palladium(ii)acetate is found to be an efficient catalyst for the single-step conversion of secondary propargyl alcohols to 1,3-diarylpropanone derivatives under mild basic conditions.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ02972J

Reference61 articles.

1. 2‐Propargyl Alcohols in Organic Synthesis

2. Gold Catalyzed Synthesis of Substituted Furan by Intermolecular Cascade Reaction of Propargyl Alcohol and Alkyne