Effect of Lewis acid bulkiness on the stereoselectivity of Diels–Alder reactions between acyclic dienes and α,β-enals

Author:

Yepes Diana12345,Pérez Patricia12345,Jaque Pablo12345,Fernández Israel678910ORCID

Affiliation:

1. Departamento de Ciencias Químicas

2. Facultad de Ciencias Exactas

3. Universidad Andres Bello

4. Santiago

5. Chile

6. Departamento de Química Orgánica I

7. Facultad de Ciencias Químicas

8. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

9. Universidad Complutense de Madrid

10. 28040-Madrid

Abstract

The influence of Lewis acid bulkiness on the stereoselectivity of Diels–Alder reactions is analysed computationally in detail.

Funder

Ministerio de Economía y Competitividad

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference131 articles.

1. Synthesen in der hydroaromatischen Reihe

2. F. Fringuelli and A.Taticchi, The Diels-Alder Reaction: Selected Practical Methods, John Wiley & Sons, Ltd, Hoboken, NJ, 2002

3. S. Sankararaman , Pericyclic Reactions – A Textbook: Reactions, Applications and Theory, Wiley, Weinheim, 2005

4. The Diels-Alder Reaction in Total Synthesis

5. Recent Advances in Natural Product Synthesis by Using Intramolecular Diels−Alder Reactions

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