Radical mechanism of a nucleophilic reaction depending on a two-dimensional structure
Author:
Affiliation:
1. College of Polymer Science and Engineering
2. State Key Laboratory of Polymer Material and Engineering
3. Sichuan University
4. Chengdu 610065
5. People's Republic of China
Abstract
This study reveals the radical mechanism of the nucleophilic substitution reaction of fluorinated graphene depending on its two-dimensional structure, which can be used to represent the chemistry characteristics of two-dimensional materials while enriching the research on nucleophilic substitution in the field of organic chemistry.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP06708A
Reference56 articles.
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4. 55. Mechanism of substitution at a saturated carbon atom. Part IV. A discussion of constitutional and solvent effects on the mechanism, kinetics, velocity, and orientation of substitution
5. Reactivity trends and stereospecificity in nucleophilic substitution reactions
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