Radical mechanism of a nucleophilic reaction depending on a two-dimensional structure

Author:

Lai Wenchuan12345ORCID,Yuan Yuehui12345,Wang Xu12345,Liu Yang12345,Li Yulong12345,Liu Xiangyang12345ORCID

Affiliation:

1. College of Polymer Science and Engineering

2. State Key Laboratory of Polymer Material and Engineering

3. Sichuan University

4. Chengdu 610065

5. People's Republic of China

Abstract

This study reveals the radical mechanism of the nucleophilic substitution reaction of fluorinated graphene depending on its two-dimensional structure, which can be used to represent the chemistry characteristics of two-dimensional materials while enriching the research on nucleophilic substitution in the field of organic chemistry.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference56 articles.

1. C. K. Ingold , Structure and mechanism in organic chemistry , Cornell University Press , Ithaca, New York , 1953

2. L. P. Hammett , Physical organic chemistry , 1940

3. M. B. Smith and J.March , March's advanced organic chemistry: reactions, mechanisms, and structure , John Wiley & Sons , 2007

4. 55. Mechanism of substitution at a saturated carbon atom. Part IV. A discussion of constitutional and solvent effects on the mechanism, kinetics, velocity, and orientation of substitution

5. Reactivity trends and stereospecificity in nucleophilic substitution reactions

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