Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium(iv)–silyl–phosphino

Fragmentation, catenation, and direct functionalisation of white phosphorus by a uranium(iv)–silyl–phosphino–carbene complex

Published:2021 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Boronski Josef T.¹²³⁴^ORCID,Seed John A.¹²³⁴^ORCID,Wooles Ashley J.¹²³⁴^ORCID,Liddle Stephen T.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. The University of Manchester

3. Manchester

4. UK

Abstract

Unprecedented insertion of P₄ into a MC double bond is reported, revealing overall catenation via P₄-fragmentation into R₂CP₂ units.

Funder

FP7 Ideas: European Research Council

Engineering and Physical Sciences Research Council

University of Manchester

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01741A

Reference73 articles.

1. Phosphorus recovery and recycling – closing the loop

2. Let’s Make White Phosphorus Obsolete

3. Phosphorus: Too Big to Fail

4. Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

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