A rare-earth-mediated conversion of white phosphorus into PBn<sub>3</sub> and highly functionalized norbornane-P<sub>7</sub>-Reference-Cited by-同舟云学术

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A rare-earth-mediated conversion of white phosphorus into PBn₃ and highly functionalized norbornane-P₇

Published:2024 Issue:2 Volume:11 Page:478-486
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhang Fangjun¹,Han Keyu¹,Cai Jiamin¹,Ye Zihao¹^ORCID,Zhang Jie¹^ORCID,Zhou Xigeng¹^ORCID,Li Zhiming¹^ORCID

Affiliation:

1. Department of Chemistry, Fudan University, No. 2005, Songhu Road, Shanghai 200438, China

Abstract

A rare-earth promoted catalytic-like conversion of P4 to organic PBn3 (I) and highly functionalized norbornane-BnP7(SiMe3)4 (II) has been realized by a stepwise reaction of TpMe2LuCl2(THF) with KBn, P4, and Me3SiCl.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D3QI02007J

Reference74 articles.

1. Lipoid Solubility as a Factor in the Toxicity of Contact Insecticides

2. Spherical Aromaticity of Inorganic Cage Molecules

3. Coordination chemistry of elemental phosphorus

4. Molecular Pnictogen Activation by Rare Earth and Actinide Complexes

5. The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity

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