Intramolecular trapping of spiro radicals to produce unusual cyclization products from usual migration substrates-Reference-Cited by-同舟云学术

Intramolecular trapping of spiro radicals to produce unusual cyclization products from usual migration substrates

Published:2023 Issue:9 Volume:14 Page:2461-2466
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Jingming¹,Liu Chengkou¹,Qiao Yaqi¹,Wei Minghui¹,Guan Wenjing¹,Mao Ziren¹,Qin Hong¹,Fang Zheng¹^ORCID,Guo Kai¹²^ORCID

Affiliation:

1. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, 211816, China

2. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 211816, China

Abstract

Unusual, highly complex and valuable spirocyclic compounds were produced through domino radical addition, intramolecular cyclization and ring opening instead of usual migration to the difunctionalization products of olefins.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05768A

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