Diastereoselective additions of H-phosphinates to alkenyl ketones under phase-transfer conditions-Reference-Cited by-同舟云学术

Diastereoselective additions of H-phosphinates to alkenyl ketones under phase-transfer conditions

Published:2022 Issue:44 Volume:58 Page:6441-6444
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yadavalli Krishna P.¹,Cummines Johannah E.¹,Carlisle Chace J.¹,Lepore Salvatore D.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431-0991, USA

Abstract

Additions of bulky H-phosphinates to β,β-disubstituted vinyl ketones under the action of a phase transfer-catalyst led to a new class of carbon quaternary center-containing phosphinates in high diastereoselectivities.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02090D

Reference24 articles.

1. Remarkable Potential of the α-Aminophosphonate/Phosphinate Structural Motif in Medicinal Chemistry

2. Triple-Helical Transition State Analogues: A New Class of Selective Matrix Metalloproteinase Inhibitors

3. Efficient synthesis of Fmoc-protected phosphinic pseudodipeptides: Building blocks for the synthesis of matrix metalloproteinase inhibitors

4. Synthesis of β-Aminophosphonates and -Phosphinates

5. Phosphinate esters as novel warheads for activity-based probes targeting serine proteases

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