Bulky magnesium(<scp>ii</scp>) and sodium(<scp>i</scp>) bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates-Reference-Cited by-同舟云学术

Bulky magnesium(ii) and sodium(i) bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates

Published:2023 Issue:3 Volume:14 Page:566-572
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhao Xue¹,Ratanasak Manussada²^ORCID,Kon Kazumasa¹³,Hasegawa Jun-ya²^ORCID,Ishihara Kazuaki³^ORCID

Affiliation:

1. Graduate School of Engineering, Nagoya University, B2-3(611) Furo-cho, Chikusa, Nagoya 464-8603, Japan

2. Section of Theoretical Catalytic Chemistry, Institute for Catalysis, Hokkaido University, Sapporo, Hokkaido 011-0021, Japan

3. Venture Business Laboratory, Nagoya University, B2-4 Furo-cho, Chikusa, Nagoya 464-0814, Japan

Abstract

Bulky Mg(ii) and Na(i) bisphenoxides have been developed as extremely effective catalysts for the chemoselective transesterification of methyl (meth)acrylates. Plausible mechanisms are proposed based on the results of XRD and DFT calculations.

Funder

Japan Society for the Promotion of Science

Takahashi Industrial and Economic Research Foundation

Nagoya University

Hokkaido University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05413B

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