Vitrimerization of crosslinked poly(ethylene-vinyl acetate): the effect of catalysts-Reference-Cited by-同舟云学术

Vitrimerization of crosslinked poly(ethylene-vinyl acetate): the effect of catalysts

Published:2024 Issue: Volume: Page:
ISSN:2755-371X
Container-title:RSC Applied Polymers
language:en
Short-container-title:RSC Appl. Polym.

Author:

Jamei Oskouei Amin¹^ORCID,Mao Erqian²,Gray Thomas G.²^ORCID,Bandegi Alireza¹,Mitchell Sarah³^ORCID,Sing Michelle K.³^ORCID,Kennedy Jayme³,Miller McLoughlin Kimberly³^ORCID,Manas-Zloczower Ica¹

Affiliation:

1. Department of Macromolecular Science and Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, USA

2. Department of Chemistry, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, USA

3. Braskem America, 550 Technology Drive, Pittsburgh, PA 15219, USA

Abstract

DFT calculations and experiments with four zinc salts as transesterification catalysts show discrepancies between computational and experimental flow activation energies, highlighting the importance of catalyst thermal stability and molecular size.

Funder

Advanced Materials and Manufacturing Technologies Office

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/LP/D4LP00112E

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