Homo- and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexes

Author:

Arroyo Marta12345,Gómez-Iglesias Patricia12345,Antón Noelia12345,García-Rodríguez Raúl12345,Alegria Elisabete C. B. A.678910,Pombeiro Armando J. L.678910,Miguel Daniel12345,Villafañe Fernando12345

Affiliation:

1. GIR MIOMeT-IU Cinquima-Química Inorgánica

2. Facultad de Ciencias

3. Campus Miguel Delibes

4. Universidad de Valladolid

5. 47011 Valladolid, Spain

6. Centro de Química Estrutural

7. Complexo I

8. Instituto Superior Técnico

9. Universidade de Lisboa

10. 1049-001 Lisboa, Portugal

Abstract

Heteropolymetallic complexes with pyridylpyrazolates bridging Mn and Na or K are tetrametallic and contain bridging pyridylpyrazolates with an unprecedented coordination mode, whereas the Mn/Li complex is bimetallic.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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