Structural, magnetic and Mössbauer spectroscopic studies of the [Fe(3-bpp)2](CF3COO)2 complex: role of crystal packing leading to an incomplete Fe(ii) high spin ⇋ low spin transition-Reference-Cited by-同舟云学术

Structural, magnetic and Mössbauer spectroscopic studies of the [Fe(3-bpp)2](CF3COO)2 complex: role of crystal packing leading to an incomplete Fe(ii) high spin ⇋ low spin transition

Published:2021 Issue:15 Volume:23 Page:2854-2861
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Sugiyarto Kristian Handoyo¹²³^ORCID,Onggo Djulia⁴⁵⁶³^ORCID,Akutsu Hiroki⁷⁸⁹¹⁰^ORCID,Reddy Varimalla Raghavendra¹¹¹²¹³^ORCID,Sutrisno Hari¹²³^ORCID,Nakazawa Yasuhiro⁷⁸⁹¹⁰^ORCID,Bhattacharjee Ashis¹⁴¹⁵¹⁶¹³^ORCID

Affiliation:

1. Department of Chemistry Education

2. Yogyakarta State University

3. Indonesia

4. Inorganic and Physical Chemistry Research Division

5. Institut Teknologi

6. Bandung

7. Graduate School of Science

8. Osaka University

9. Osaka

10. Japan

11. IUC DAE CSR

12. Indore

13. India

14. Department of Physics

15. Visva-Bharati University

16. Santiniketan

Abstract

Mononuclear complex [Fe(3-bpp)₂](CF₃COO)₂ exhibits a thermal (HS + HS) ⇋ (HS + LS) transition at ∼226 K which is not associated with any crystallographic transition.

Funder

Yogyakarta State University

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CE/D0CE01687J

Reference48 articles.

1. P. Gütlich and H. A.Goodwin , in Spin Crossover in Transition Metal Compounds I , Springer , 2004 , pp. 1–47

2. M. A. Halcrow , Spin-Crossover Materials: Properties and Applications , John Wiley & Sons , 2013