A mononuclear Fe(<scp>iii</scp>) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour-Reference-Cited by-同舟云学术

A mononuclear Fe(iii) complex showing thermally induced spin crossover and slow magnetic relaxation with reciprocating thermal behaviour

Published:2024 Issue:26 Volume:53 Page:10824-10828
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bridová Terézia¹,Rajnák Cyril¹^ORCID,Titiš Ján¹^ORCID,Samoľová Erika²^ORCID,Tran Kevin³^ORCID,Malina Ondřéj⁴⁵^ORCID,Bieńko Alina⁶^ORCID,Renz Franz³^ORCID,Gembický Milan⁷^ORCID,Boča Roman⁸^ORCID

Affiliation:

1. Faculty of Natural Sciences, University of Ss. Cyril and Methodius, 917 01 Trnava, Slovakia

2. Institute of Physics of the Czech Academy of Sciences, 182 21 Prague, Czech Republic

3. Institute of Inorganic Chemistry, Leibniz University, Hannover, D-30167, Germany

4. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University Olomouc, Olomouc, Czech Republic

5. Nanotechnology Centre, Centre of Energy and Environmental Technologies, VŠB–Technical University of Ostrava, Ostrava-Poruba, Czech Republic

6. Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie, 50-383 Wroclaw, Poland

7. X-ray Crystallography Facility, UC San Diego, 5128 Urey Hall MC 0358, 9500 Gilman Drive, La Jolla, CA 92093, USA

8. Faculty of Health Sciences, University of Ss. Cyril and Methodius, 917 01 Trnava, Slovakia

Abstract

AC susceptibility measurements of [FeIII(L5)(NCSe)] reveal a field supported slow magnetic relaxation with the sign of reciprocating thermal behaviour. The complex exhibits thermally induced spin crossover centred at T1/2 = 281 K.

Funder

Agentúra na Podporu Výskumu a Vývoja

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00642A

Reference56 articles.

1. Über die magnetische Susceptibilität der komplexen Verbindungen

2. Über die magnetische Susceptibilität der komplexen Verbindungen (II. Mitteil.).

3. Magnetismus und Polymorphie innerer Komplexsalze: Eisensalze der Dithiocarbamidsäuren

4. Spin Transitions in six-coordinate iron(II) complexes

5. Spin crossover in iron(II)-complexes