Magnetic relaxation in a Co(ii) chain complex: synthesis, structure, and DFT computational coupling constant

Author:

Wu Wen-Hao12345,Wang Ya-Qun12345,Mi Hong-Li12345,Xue Qing-Xuan12345,Shao Feng678910ORCID,Shen Fei1112131415,Yang Feng-Lei12345ORCID

Affiliation:

1. School of Chemistry and Material Science and

2. Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials

3. Jiangsu Normal University

4. Xuzhou

5. P. R. China

6. Institut de Chimie Moléculaire et des Matériaux d'Orsay

7. CNRS

8. Université Paris-Sud, Université Paris-Saclay

9. 91405 Orsay Cedex

10. France

11. College of Physical Education and

12. Health & Education Ministry Key Laboratory of Adolescent Health Assessment and

13. Exercise Intervention of Ministry of Education

14. East China Normal University

15. Shanghai 200241

Abstract

We report a homospin non-solvated CoII chain compound constructed by two similar tridentate ligands and chloride ions, which displays slow magnetic relaxation below 5 K.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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