Auxiliary-assisted palladium-catalyzed halogenation of unactivated C(sp3)–H bonds at room temperature-Reference-Cited by-同舟云学术

Auxiliary-assisted palladium-catalyzed halogenation of unactivated C(sp3)–H bonds at room temperature

Published:2016 Issue:38 Volume:52 Page:6423-6426
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yang Xinglin¹²³⁴⁵,Sun Yonghui¹²³⁴⁵,Sun Tian-yu⁶⁷⁸⁹¹⁰,Rao Yu¹²³⁴⁵

Affiliation:

1. MOE Key Laboratory of Protein Sciences

2. Department of Pharmacology and Pharmaceutical Sciences

3. School of Medicine

4. Tsinghua University

5. Beijing 100084

6. Lab of Computational Chemistry and Drug Design

7. Key Laboratory of Chemical Genomics

8. Peking University Shenzhen Graduate School

9. Shenzhen 518055

10. China

Abstract

The direct transformation of unactivated C(sp³)–H bonds into C-halogen bonds was achieved by palladium catalysis at room temperature with good functional group tolerance.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC00234J

Reference85 articles.

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2. Nature's Inventory of Halogenation Catalysts: Oxidative Strategies Predominate

3. Efficient preparation of intermediates corresponding to C22-C27 and C28-C34 of FK-506

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