Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex-Reference-Cited by-同舟云学术

Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex

Published:2020 Issue:27 Volume:11 Page:7144-7157
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cowie Bradley E.¹²³⁴^ORCID,Douair Iskander⁵⁶⁷⁸⁹,Maron Laurent⁵⁶⁷⁸⁹^ORCID,Love Jason B.¹²³⁴^ORCID,Arnold Polly L.¹²³⁴^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh

4. UK

5. Université de Toulouse

6. INSA

7. UPS

8. CNRS

9. UMR 5215

Abstract

A U^IV/U^IV “Pacman” complex exhibits facile oxo-ligand functionalisation and substitution reactivity, owing to a bridging catecholate ligand that enhances the μ-oxo nucleophilicity and stabilises the resulting products.

Funder

Office of Science

University of Edinburgh

Engineering and Physical Sciences Research Council

Natural Sciences and Engineering Research Council of Canada

European Research Council

Alexander von Humboldt-Stiftung

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02297G

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