Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex-Reference-Cited by-同舟云学术

Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex

Published:2020 Issue:27 Volume:11 Page:7144-7157
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cowie Bradley E.¹²³⁴^ORCID,Douair Iskander⁵⁶⁷⁸⁹,Maron Laurent⁵⁶⁷⁸⁹^ORCID,Love Jason B.¹²³⁴^ORCID,Arnold Polly L.¹²³⁴^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh

4. UK

5. Université de Toulouse

6. INSA

7. UPS

8. CNRS

9. UMR 5215

Abstract

A U^IV/U^IV “Pacman” complex exhibits facile oxo-ligand functionalisation and substitution reactivity, owing to a bridging catecholate ligand that enhances the μ-oxo nucleophilicity and stabilises the resulting products.

Funder

Office of Science

University of Edinburgh

Engineering and Physical Sciences Research Council

Natural Sciences and Engineering Research Council of Canada

European Research Council

Alexander von Humboldt-Stiftung

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02297G

Reference56 articles.

1. Reductive coupling of carbon monoxide by U(iii) complexes—a computational study

2. Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N2, Coupling of CO, and Deoxygenation Insertion of CO2 under Ambient Conditions

3. The Bond between CO and Cp′3U in Cp′3U(CO) Involves Back-bonding from the Cp′3U Ligand-Based Orbitals of π-Symmetry, where Cp′ Represents a Substituted Cyclopentadienyl Ligand

4. Chemistry of trivalent uranium metallocenes: electron-transfer reactions with carbon disulfide. Formation of [(RC5H4)3U]2[.mu.-.eta.1.eta.2-CS2]

5. Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Arene-, Chlorido-, and Imido-Uranium Bis- and Tris(boryloxide) Complexes;Inorganic Chemistry;2024-04-01

2. Synthesis and Characterization of Isostructural Th(IV) and U(IV) Pyridine Dipyrrolide Complexes;Inorganic Chemistry;2024-02-20

3. Structure and bonding of a radium coordination compound in the solid state;Nature Chemistry;2023-11-09

4. Photocatalytic oxidative cleavage of aryl alkene CC bonds using a uranyl cation;Organic Chemistry Frontiers;2023

5. Palladium complexes bearing calixpyrrole ligands with pendant hydrogen bond donors: Synthesis, structural characterization, electrochemistry and dihydrogen evolution;Polyhedron;2022-10