The Bond between CO and Cp′3U in Cp′3U(CO) Involves Back-bonding from the Cp′3U Ligand-Based Orbitals of π-Symmetry, where Cp′ Represents a Substituted Cyclopentadienyl Ligand-Reference-Cited by-同舟云学术

The Bond between CO and Cp′3U in Cp′3U(CO) Involves Back-bonding from the Cp′3U Ligand-Based Orbitals of π-Symmetry, where Cp′ Represents a Substituted Cyclopentadienyl Ligand

Published:2009-06-16 Issue:13 Volume:28 Page:3629-3635
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Maron Laurent¹,Eisenstein Odile²,Andersen Richard A.³

Affiliation:

1. LPCNO, Université de Toulouse, INSA, UPS, LPCNO, 135 Avenue de Rangueil, F-31077 Toulouse, France, and CNRS, LPCNO, F-31077 Toulouse, France

2. Institut Charles Gerhardt, Université Montpellier 2, CNRS 5253, case courrier 1501, Place E. Bataillon, 34095 Montpellier France

3. Department of Chemistry and Chemical Sciences Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720-1460

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om801098b

Reference59 articles.

1. Preparation of the first molecular carbon monoxide complex of uranium, (Me3SiC5H4)3UCO

2. The f-orbital to carbonyl 2.pi. back-bonding: the electronic structures of (.eta.5-C5H5)3UCO and (.eta.5-C5H5)3UOC

3. Synthesis and Single Crystal X-ray Diffraction Study on the First Isolable Carbonyl Complex of an Actinide, (C5Me4H)3U(CO)

4. Carbon Monoxide and Isocyanide Complexes of Trivalent Uranium Metallocenes

5. Comparative Reactivity of Sterically Crowded nf3 (C5Me5)3Nd and (C5Me5)3U Complexes with CO: Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex

Cited by 65 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Scandium(II) Carbonyl Complex (C₅H₂^tBu₃)₂Sc(CO) and Its Isocyanide Analog (C₅H₂^tBu₃)₂Sc(CNC₆H₃Me₂-2,6);Journal of the American Chemical Society;2024-08-27

2. Bis(acyl)phosphide Complexes of U(III)/U(IV): A Case of a Hidden Redox-Active Ligand;Inorganic Chemistry;2024-05-15

3. Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?;Inorganic Chemistry;2024-05-13

4. N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners;Journal of the American Chemical Society;2024-04-03

5. Spectroscopic and Computational Evidence of Uranium Dihydrogen Complexes;Journal of the American Chemical Society;2024-01-08