A new chiral dimanganese(iii) complex: synthesis, crystal structure, spectroscopic, magnetic, and catalytic properties

Author:

Dinca Alina S.12345,Candu Natalia32675,Shova Sergiu895,Lloret Francesc1011121314,Julve Miguel1011121314,Parvulescu Vasile I.32675,Andruh Marius12345

Affiliation:

1. Inorganic Chemistry Laboratory

2. Faculty of Chemistry

3. University of Bucharest

4. 020464-Bucharest

5. Romania

6. Department of Organic Chemistry, Biochemistry and Catalysis

7. Bucharest

8. “Petru Poni” Institute of Macromolecular Chemistry

9. RO-700487 Iasi

10. Departament de Química Inorgànica

11. Instituto de Ciencia Molecular

12. Facultat de Química de la Universitat de València

13. 46980 Paterna

14. Spain

Abstract

The two enantiomeric dimanganese(iii) complexes are efficient catalysts, with a total enantioselectivity, in the epoxidation of methyl trans-cinnamate.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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