Chiral cadmium–amine complexes for stimulating non-linear optical activity and photoluminescence in solids based on aurophilic stacks-Reference-Cited by-同舟云学术

Chiral cadmium–amine complexes for stimulating non-linear optical activity and photoluminescence in solids based on aurophilic stacks

Published:2024 Issue: Volume: Page:
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Boidachenko Kseniia¹²^ORCID,Liberka Michal¹²^ORCID,Wang Junhao³,Tokoro Hiroko³^ORCID,Ohkoshi Shin-ichi⁴^ORCID,Chorazy Szymon¹^ORCID

Affiliation:

1. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland

2. Doctoral School of Exact and Natural Sciences, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków, Poland

3. Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

4. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

Cd(ii) complexes with chiral amines play a dual role in materials incorporating aurophilic stacks, first, in breaking the symmetry to generate NLO activity, and second, in governing the Au⋯Au distances to give tunable charge transfer luminescence.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D4TC01042F

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