Asymmetric synthesis of atropisomeric arylpyrazoles <i>via</i> direct arylation of 5-aminopyrazoles with naphthoquinones-Reference-Cited by-同舟云学术

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Asymmetric synthesis of atropisomeric arylpyrazoles via direct arylation of 5-aminopyrazoles with naphthoquinones

Published:2024 Issue:21 Volume:22 Page:4254-4263
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Liu Jiamin¹,Wei Xingfu¹,Wang Yue¹,Qu Jingping¹^ORCID,Wang Baomin¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Department of Pharmaceutical Engineering, School of Chemical Engineering, Dalian University of Technology, 2 Linggong Road, Dalian 116024, China

Abstract

The direct arylation realizes the transform of central into axial chirality, and successfully synthesizes atropisomeric arylpyrazoles.

Funder

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00514G

Reference53 articles.

1. Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

2. Recent encounters with atropisomerism in drug discovery

3. Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

4. Biological Stereoselectivity of Atropisomeric Natural Products and Drugs

5. Fragment-Based Discovery of MRTX1719, a Synthetic Lethal Inhibitor of the PRMT5•MTA Complex for the Treatment of MTAP-Deleted Cancers

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