Reversible single-crystal-to-single-crystal photoisomerization of a silver(i) macropolyhedral borane
Author:
Affiliation:
1. N. S. Kurnakov Institute of General and Inorganic Chemistry RAS
2. 119991 Moscow, Russian Federation
3. A. N. Nesmeyanov Institute of Organoelement Compounds RAS
Abstract
A reversible conversion of [trans-B20H18]2− to [iso-B20H18]2− and linkage isomerism occur in a single crystal of {Ag2(PPh3)6[B20H18]} (the positions of [Ag(PPh3)3]+ are shown in red and blue).
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CE/C5CE00859J
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