Reduced 0.418 V VOC-deficit of 1.73 eV wide-bandgap perovskite solar cells assisted by dual chlorides for efficient all-perovskite tandems

Author:

Zhao Yue12,Wang Changlei12,Ma Tianshu12,Zhou Luwei12,Wu Zhanghao12,Wang Huayang12,Chen Cong3,Yu Zhenhua4,Sun Weiwei5,Wang Aolin6,Huang Hao6,Zou Bingsuo6ORCID,Zhao Dewei3ORCID,Li Xiaofeng12ORCID

Affiliation:

1. School of Optoelectronic Science and Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, China

2. Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province & Key Lab of Modern Optical Technologies of Education Ministry of China, Soochow University, Suzhou 215006, China

3. College of Materials Science and Engineering, Engineering Research Center of Alternative Energy Materials & Devices, Ministry of Education, Sichuan University, Chengdu 610065, China

4. Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan 430072, China

5. College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China

6. Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China

Abstract

Synergistic effects of lead chloride and phenethylammonium chloride suppress the phase segregation and non-radiative recombination in 1.73 eV wide-Eg perovskite solar cells (PSCs), leading to a significantly reduced VOC-deficit to 0.418 V.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Natural Science Foundation of Jiangsu Province

Natural Science Research of Jiangsu Higher Education Institutions of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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